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Clorox Commercial Solutions Germicidal Bleach4, Regular, Professional Use-07/03/2019
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaClorox Commercial Solutions Clorox Germicidal Bleach 4 with a concentration level of 8.25 percent is EPA-registered to kill Salmonella typhi to pass the food-contact sanitizer test. Clorox Germicidal Bleach 4 goes one step further with claims on both E. coli and listeria in addition to salmonella.
Purpose of product.
Usage: Laundry bleach and hardsurface disinfectant cleanerStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20241221 Broadway
Oakland CA 94612
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 007732-18-5 -- -- -- -- -- 007681-52-9 -- 5.0-10.0 C, N -- -- -- -- 007647-14-5 -- -- -- -- -- 007775-09-9 -- -- -- -- -- 026062-79-3 -- -- -- -- -- 001310-73-2 -- C -- -- -- -- 068479-09-4 -- -- -- -- -- 000497-19-8 -- Xi -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
Chemical Function Purpose served by this chemical.Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Water
Solvent
007732-18-5
231-791-2-- No -- -- -- No No Sodium hypochlorite
Antimicrobial Active
007681-52-9
231-668-35.0-10.0 No H314, H400, EUH031 -- No No Sodium chloride
Thickener
007647-14-5
231-598-3-- No -- -- -- No No Sodium chlorate
Non-Functional Constituent
007775-09-9
231-887-4-- No H271, H302, H411 P501, P210, P220, P221, P264, P270, P273, P280, P283, P308+P313, P370+P380, P375, P378 No No Polyquaternium-6
Polymer
026062-79-3
--- No -- -- -- Yes No Sodium hydroxide
pH Adjuster
001310-73-2
215-185-5-- No H290, H314, H315, H319 P260, P280, P303+P361+P353, P305+P351+P338, P310 No No 2-Propenoic acid, telomer with sodium sulfite (1:1), sodium salt
Antiredeposition Agent
068479-09-4
---- No -- -- -- No No Sodium carbonate
Alkalinity builder
000497-19-8
207-838-8-- No H319 P264, P280, P305+P351+P338, P337+313 No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H271 : May cause fire or explosion; strong oxidizerH290 : May be corrosive to metalsH302 : Harmful if swallowedH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH319 : Causes serious eye irritationH400 : Very toxic to aquatic lifeH411 : Toxic to aquatic life with long lasting effectsEUH031 : Contact with acids liberates toxic gas
- P210 : Keep away from heat/sparks/open flames/hot surfacesP220 : Keep/Store away from clothing/…/combustible materialsP221 : Take any precaution to avoid mixing with combustibles…P260 : Do not breathe dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP270 : Do not eat, drink or smoke when using this productP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP283 : Wear fire/flame resistant/retardant clothingP310 : Immediately call a POISON CENTER or doctor/physicianP375 : Fight fire remotely due to the risk of explosionP378 : Use … for extinctionP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP308+P313 : If exposed or concerned: Get medical advice/attentionP370+P380 : In case of fire: Evacuate areaP501 : Dispose of contents/container to
- GHS03 : OxidiserGHS05 : CorrosiveGHS07 : IrritantGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :July 03, 2019 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3 0 0 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels11.8-12.4 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard statements
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Danger. Causes severe skin burns and eye damage.
Precautionary Statements
Prevention
Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands and any exposed skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Keep only in original container.
Response
Immediately call a POISON CENTER or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting.
Absorb spillage to prevent material damage.
Storage
Store locked up.
Disposal
Dispose of contents/container to an approved waste disposal plant
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Acute health effects
From SDS:
Hazards Identification
Danger. Causes severe skin burns and eye damage.
Potential Health Effects
Eye Contact: Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage.
Skin Contact: Avoid contact with skin. Corrosive. Causes burns.
Inhalation: May cause irritation of respiratory tract. May cause pulmonary edema.
Ingestion: Ingestion causes burns of the upper digestive and respiratory tracts. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. -
Chronic health effects
From SDS:
See Carcinogenicity. -
Carcinogenicity
Sodium hypochlorite CAS No. 007681-52-9: IARC Group 3 Carcinogen.
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Handling information
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials.
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Disposal information
Do not reuse empty containers. Dispose of in accordance with federal, state and local regulations.
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California Prop. 65 Warning
This product does not contain any Proposition 65 chemicals.
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First Aid
Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Seek immediate medical attention/advice. Remove contact lenses, if present and easy to do. Continue rinsing.
Skin Contact: Wash skin with soap and water. Immediate medical attention is required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
Inhalation: Remove to fresh air. If symptoms persist, call a physician. If breathing has stopped, give artificial respiration. Get medical attention immediately. If not breathing, give artificial respiration. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur.
Ingestion: Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately.
Protection of First-Aid Personnel: Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing
Notes to Physician: Treat symptomatically. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure
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